In the end / At the end of (something)

In the end

Word form - Adverb phrase
Meaning - Eventually or finally.
Example - In the end, he decided to accept the offer.
http://dictionary.cambridge.org/dictionary/english/in-the-end

At the end of (something)

Word form - Adverb phrase
Meaning - To refer the position at the end of something.
Examples
1. I’m going to play football at the end of the week.
2. We will get the exam results at the end of May.
3. We will finish the task at the end of the day.

Remark
At the end of the day (= by the end of the day)

Reference
http://idioms.thefreedictionary.com/at+the+end+of+the+day

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